It explains how hydrogen embrittlement occurs in stainless steel. Hydrogen cracking of ferriticaustenitic stainless steel. There are several types of stress corrosion cracking scc, for example, chloride induced scc and h 2 s induced scc. The behavior of hydrogen induced slow crack growth in type 310 and type 162010 stable austenitic stainless steels along with type 321 unstable austenitic stainless steel. A small number of duplex and superduplex stainless steel components have failed in subsea service due to hydrogen induced stress cracking hisc. Hydrogeninduced cracking hic is the stepwise internal cracks that connect adjacent hydrogen blisters on different planes in the metal, or to the metal surface. Type 316 stainless steel shows a larger susceptibility to hydrogen embrittlement 1 mpa gaseous h 2 in smooth tensile bars when sensitized 973 k for 24 h compared to solutionannealed microstructures, figure 3. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. It is also explained that how to test the damage due to hydrogen embrittlement in stainless steel.
Hic is especially prevalent in iron alloys because of the restricted slip capabilities in the predominantly bodycentered cubic bcc structure. This paper presents results from a test program examining the hisc susceptibility of 25% cr super duplex stainless steel uns s32750 at temperatures up to 150 0 c. Hydrogeninduced stress cracking of swaged super duplex stainless steel subsea components, corrosion 757. Additionally, hydrogen atoms diffuse through metals and coalesce.
Hic steel hydrogen induced cracking supplier company. This includes a discussion of the mechanism by which a steel becomes embrittled by hydrgogen, circumstances that lead to embrittlement, the effects of embrittlement on steel behavior, how to prevent the embrittlement, and tests for evaluating whether a steel has been embrittled. Hydrogen damage figure 1 is encountered in many steel processes, such as pickling, electroplating and welding. This penetration can lead to the brittle fracture of materials that are normally ductile when hydrogen happens to be present in. For the precipitation strengthened austenitic stainless steel, the weld was more sensitive to fracture and hydrogeninduced failure than the base material. Hydrogen induced stress cracking hisc resistance and. Hydrogen induced cracking hic in steel is a risk problem when steels are charged with hydrogen in service as in various hydrogen sulfide environments like sour oil and gas wells and some power plants. Combining action of atomic hydrogen into hydrogen gas is a cumulative process and builds up of hydrogen gas pressure eventually leads to hydrogen induced cracking hlc.
Susceptibility to hydrogen blistering and hydrogen induced cracking can be apportioned to the quality of the steel plate used. Hydrogen induced cracking hic of austenitic stainless steel ss under mode iii loading can occur during dynamic charging of hydrogen, and the normalized threshold stress was. Home products a516gr70 hicnace tm0284 hydrogen induced cracking hydrogen induced cracking the crack sensitivity rate a516gr65 csr hic plate. The presence of hydrogen atoms in a metal degrades some of its mechanical properties, especially its ductility, leading in some cases to embrittlement. The stress induced transformation of austenite to bodycentered cubic bcc martensite has particular relevance in rationalizing the behavior of various austenitic stainless steel alloys. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. The formation of subsurface planar cavities, called hydrogen blisters, in a metal resulting from. Hydrogeninduced stress cracking of swaged super duplex. In potentially critical environments, the weld joint properties must be carefully controlled. Hydrogen embrittlement also known as hydrogen assisted cracking and hydrogeninduced cracking, describes the embrittling of metal after being exposed to hydrogen. Hydrogeninduced cracking hic in steel is a risk problem when steels are charged with hydrogen in service as in various hydrogen sulfide environments like sour oil and gas wells and some power plants. Effect of temperature in hydrogen embrittlement in stainless steel, and fusion in inox steel. Stress corrosion cracking facts and how to reduce the risk.
Hydrogen induced cracking of subsea duplex stainless steel twi. Hydrogen induced cracking hic in the oil and gas industry. Experience has shown that stainless steels can suffer from hydrogen induced stress cracking hisc under cathodic protection in seawater. G146012018 standard practice for evaluation of disbonding of bimetallic stainless alloysteel plate for use in highpressure, hightemperature refinery hydrogen service hydrogen induced cracking test specimens hightemperature service applications highpressure service applications metallography steel plates. Hydrogen cracking of ferriticaustenitic stainless steel weld. Hydrogen embrittlement of steel industrial metallurgists. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment.
Stainless steel plate carbon steel round bar alloy steel material. Hydrogeninduced cracking by nanovoids in 310 stainless steel. Hydrogeninduced cracking, or hydrogen embrittlement, is a chemical phenomenon that causes metal alloys to fracture due to a buildup of hydrogen molecules within the crystal lattice structure. The significance of these failures has led to research aimed at defining critical conditions for hisc, to allow confident design of components in future. Journal of iron and steel research international 22. The behavior of hydrogen induced slow crack growth in type 310 and type 162010 stable austenitic stainless steels along with type 321 unstable austenitic stainless steel were investigated. Libertador 8250, 1429 buenos aires, argentina abstract in t h e p r e s e n t w. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. Factors affecting inservice cracking of weld zone in. The significance of these failures has led to research to define critical loading conditions for. Also high strength structural steels which are welded are exposed to a certain hydrogen pickup which means a risk at fracture and blistering. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Hydrogen stress cracking can affect several different types of metals such as high strength structural, carbon, and low alloy steels, along with titanium, nickel, and aluminium alloys.
May 19, 2009 susceptibility to hydrogen blistering and hydrogen induced cracking can be apportioned to the quality of the steel plate used. Hydrogen damage microcracks appeared on the surface of the matrix and the weld during charging with a very large current even without any applied stress. Request pdf modelling hydrogen induced stress corrosion cracking in austenitic stainless steel a model has been developed which simulates the deformation of. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. Mechanisms that have been proposed to explain embrittlement include the formation of brittle hydrides, the creation of voids that can lead to bubbles and pressure buildup within a material and e. The significance of these failures has led to research to define critical loading conditions for hisc, to allow confident design of components in future. It is clear that in both cases, cracking occurs at many locations. Johnson 1875 on some remarkable changes produced in iron and steels by the action of hydrogen acids. This paper examines the factors determining weld metal hydrogen cracking.
Steel pipelines and pressurised equipment can operate satisfactorily for up to 8 to 10 years before any cracks are discovered. Delayed cracking also known as hydrogen induced cracking or cold cracking, occurs when the following three factors are present at the same time. This is a unique mode of mechanical failure that most commonly affects low alloys and highhardness steel grades such as titanium ti. The stressinduced transformation of austenite to bodycentered cubic bcc martensite has particular relevance in rationalizing the behavior of various austenitic stainless steel alloys. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Hydrogen embrittlement of stainless steel hydrogen diffuses along the grain boundaries and combines with the carbon, which is alloyed with the iron, to form methane gas. Hisc is a term to refer to hydrogen stress cracking hsc of duplex and super duplex stainless steels dss and sdss, respectivelywhen exposed to hydrogen generated by cathodic. Duplex and super duplex stainless steels sdss have emerged in the last decade or so, as an alternative material for harsh environments. Nevertheless, according to recent studies, sdss when cathodically protected against corrosion are prone to. These atoms are then defused through the grains, and create lattice defects. This can occur during elevatedtemperature thermal treatments and in service during electroplating, contact with maintenance chemicals, wet h 2 s, corrosion reactions, cathodic protection, and operating in highpressure hydrogen containing environments. Hydrogeninduced cracking and stress corrosion cracking of.
Naceastm g193 1 includes the following description of hydrogen blistering. The brittle nature of the fracture surface, calcareous deposits on the ferrule and exposure to cathodic protection suggested hydrogen induced stress cracking hisc. Hydrogeninduced cracking was investigated by teminsitu tension in hydrogenated stainless steel of type 310. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. On the stress corrosion cracking and hydrogen embrittlement. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Combatting the problem of hydrogen induced cracking in sour service, hic steel plate is carbon steel plates which are tested to assess the susceptibility of the material to hydrogen induced cracking. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Request pdf modelling hydrogen induced stress corrosion cracking in austenitic stainless steel a model has been developed which simulates the deformation of single crystal austenitic stainless. Hydrogen induced cracking in austeniticferritic duplex stainless steels, proc conf. The steel specimens shall be immersed into test solutions at the temperature 253c 775f.
This is a problem commonly found in wet h2ssour service operating environments such as in the oil, gas and petrochemical industry. Hydrogen induced cracking hic and the blistering of carbon steel are both such unexpected corrosion phenomenon. Hydrogen cracking in metastable austenitic stainless steels. At high hardness above about 40 hrc, steel becomes quite susceptible to cracking in the presence of hydrogen.
Hydrogeninduced cracking an overview sciencedirect topics. Hydrogen induced cracking steel features, applications. In order to evaluate the resistance to hydrogeninduced cracking of pipeline and pressure vessel steel, standard test shall be conducted in accordance with nace tm0284. The results showed that the failure developed from a combination of factors, typical for hydrogeninduced stress cracking. Type 304 is a metastable austenite, and it is very susceptible to martensite formation. The measured hydrogen content in parts of the material exceeded 40 ppm, more than an order of magnitude higher than what is normally expected in super duplex stainless steels. Corrosionpedia what is hydrogeninduced cracking hic. This article discusses hydrogen embrittlement of carbon steel. Hydrogen induced cracking results from atomic hydrogen being absorbed by solid metals.
At hardness levels above 22 hrc, steel becomes less resistant to hydrogen induced cracking and other environmental effects. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. Hydrogen cracking in duplex stainless steel weld metal. If hydrogen embrittlement takes place at room temperature, the hydrogen atoms are then absorbed into the lattice of stainless steel. Cracking occurred in welds containing 83% ferrite and hydrogen levels of 11. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Hughes 1880 note on some effects produced by the immersion of steel and iron wires in acidulated water. Otherwise, in the case of lowerc h, hydrogen enhances ductile fracture via. The stress thus induced causes cracking, and the path is called transgranular. In the case of a crystal lattice becoming saturated. Hydrogeninduced cracking of carbon seamless steel tube. Hydrogen induced cracking hic occurs when carbon steel is exposed to hydrogen sulphide h 2 s and is the direct result of electrochemical corrosion reactions between the sour service or wet h 2 s environment. Modelling hydrogen induced stress corrosion cracking in.
Astm g146 012018 standard practice for evaluation of. Hydrogen induced cracking steel features, applications and. The formation of subsurface planar cavities, called hydrogen blisters, in a metal resulting from excessive internal hydrogen pressure. G146012018 standard practice for evaluation of disbonding of bimetallic stainless alloy steel plate for use in highpressure, hightemperature refinery hydrogen service hydrogen induced cracking test specimens hightemperature service applications highpressure service applications metallography steel plates. Nov 28, 2018 hydrogen induced cracking, or hydrogen embrittlement, is a chemical phenomenon that causes metal alloys to fracture due to a buildup of hydrogen molecules within the crystal lattice structure. Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause atomic hydrogen to penetrate hardened or higher strength steels and cause stress cracking. The results showed that the failure developed from a combination of factors, typical for hydrogen induced stress cracking. The factors of hydrogen embrittlement and ways to prevent it is. Abstract a recent subsea failure of two subsea connectors made of uns s32760, a 25 wt% cr super duplex stainless steel, led to an extensive root cause failure analysis. An illustration of cracking associated with the hydrogen embrittlement of austenitic stainless steel that is pulled in tension.
Another type of hydrogen corrosion, stressorientated hydrogen induced cracking sochic, is normally found in the base metal adjacent to the weld, where the stress point is highest due to the internal pressure of the vessel and the stress on the weld point itself. With regards to sour corrosion, the rate of hydrogen entry into the subsurface of a steel subject to sour corrosion is now well known to vary as h2s0. Also high strength structural steels which are welded are exposed to a certain hydrogen pickup which means a risk at fracture and blistering due to hic. Technical reference on hydrogen compatibility of materials. A model has been developed which simulates the deformation of single crystal austenitic stainless steels and captures the effects of hydrogen on stress corrosion cracking. Previous work using slow strain rate testing3,4 had shown that these grades were susceptible to hydrogen embrittlement when exposed to cp s below 700mv sce. This type of austenitic stainless steels was used extensively in investigating hydrogen embrittlement behavior because of its material composition, structure instability, intergranular cracking mode, and ability to phase transform upon hydrogen charging or induced strain. Hydrogeninduced cracking of carbon seamless steel tube materials date.
Hydrogeninduced cracking of carbon seamless steel tube materials carbon seamless steel tube are mainly used for transporting high pressure oil and gas near the wellhead. Hydrogen cracking in metastable austenitic stainless. Nov 21, 2018 an illustration of cracking associated with the hydrogen embrittlement of austenitic stainless steel that is pulled in tension. Hydrogen transport, microstructure, and hydrogen induced. Aug 01, 2019 hydrogen induced stress cracking of swaged super duplex stainless steel subsea components, corrosion 757. Effect of microstructure on hydrogeninduced cracking of.
Hydrogen induced stress cracking of swaged super duplex. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Jun 27, 2019 the brittle nature of the fracture surface, calcareous deposits on the ferrule and exposure to cathodic protection suggested hydrogen induced stress cracking hisc. A corrosive medium especially chloridebearing or hydrogen sulphide h 2 s media. The programme sought to generate cracking data for sma welds, in 22%cr duplex stainless steel, for which the consumable hydrogen level had been determined using the vhe method. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Jul 29, 2019 combining action of atomic hydrogen into hydrogen gas is a cumulative process and builds up of hydrogen gas pressure eventually leads to hydrogen induced cracking hlc.
Another type of hydrogen corrosion, stressorientated hydrogen induced cracking sochic, is normally found in the base metal adjacent to the weld, where the stress point is highest due to the internal pressure of the. This article explains all about hydrogen embrittlment in stainless steel. Miura m and ogawa k, hydrogen embrittled cracking in duplex stainless steel weld metal, iiw doc ix146187. Duplex stainless steels 86, the hague, the netherlands, 2628 october 1986, nederlands institut voor latechniek, 1986, paper 26, 268279. Hydrogen induced stress cracking of duplex stainless steel. It was found experimentally that hydrogeninduced cracking happens via nanovoid nucleation followed by quasicleavage along 111 planes whenc h is higher. No wonder steel can be susceptible to hydrogen cracking. Hydrogeninduced cracking hic is most commonly encountered in steels but other metals are susceptible, as shown in table 33. In order for heat affected zone cracking to occur, three. The most important hydrogen promoter industrially, and probably the most vigorous,2 is h2s, sour gas. Hydrogeninduced cracking of weld metal of austenitic. Hydrogen induced cracking of subsea duplex stainless steel.
176 121 340 1428 983 1100 490 34 1554 1554 342 1004 606 582 1347 765 38 191 813 1463 35 942 946 1164 326 54 375 780 134 1320 637 253 763 1404 906 1027 875 600 1250 537 373 820